CD1
01. Time to Say Goodbye (Con te partirò) [Sarah's Intimate Version] - Sarah Brightman
02. The Prayer - Jonathan & Charlotte & Only Boys Aloud
03. Regresa a mi (Unbreak My Heart) - Il Divo
04. Les Misérables: I Dreamed a Dream - Susan Boyle
05. Carousel: You'll Never Walk Alone - Alfie Boe
06. Man of La Mancha: The Impossible Dream - Richard & Adam
07. La Vie En Rose - Katherine Jenkins
08. Jerusalem - Russell Watson
09. Requiem: Pie Jesu - Charlotte Church
10. La Bohème, Act I: “Che gelida manina” - Paul Potts, The City of Prague Philharmonic Orchestra & Richard Haines
11. South Pacific: Some Enchanted Evening - José Carreras
12. Calon Lân - Only Boys Aloud
13. Amazing Grace - The Priests
14. Madame Butterfly, Act II: “Un bel di” (One Fine Day) [The Official ITV World Cup 2002 Theme] - OperaBabes
15. When You Wish upon a Star (From "Pinocchio") - Jackie Evancho
16. Carmina Burana: O Fortuna - Rhydian, Simon Lee & The Marylebone Camerata Orchestra

CD2
01. Perhaps Love - John Denver & Plácido Domingo
02. Caruso - Vittorio Grigolo, Pier Giorgio Morandi, Orchestra del Teatro Regio di Parma & Martino Faggiani
03. Turandot, Act III: “Nessun dorma” - Johan Botha, Radio Symphony Orchestra Vienna & Paolo Carignani
04. Gianni Schicchi, Act III “O mio babbino caro” - Dame Kiri Te Kanawa, Sir John Pritchard & London Philharmonic Orchestra
05. Whisper of Angels - Amici Forever
06. Angel - Angelis
07. Pagliacci, Act I: “Vesti la giubba” - Michael Bolton, Steven Mercurio & Philharmonia Orchestra
08. Nights in White Satin (Notte di luce) - Mario Frangoulis & Justin Hayward
09. The Toast of New Orleans: Be My Love - Mario Lanza
10. Panis Angelicus - Lesley Garrett, Britten Sinfonia & Ivor Bolton
11. Carmen, Act 1: “L'amour est un oiseau rebelle" (Habanera) - Maria Callas, Orchestre de l'Opéra National de Paris, Choeurs Rene Duclos & Georges Prêtre
12. West Side Story: “Somewhere” - Michael Ball
13. Who Wants to Live Forever - Sarah Brightman
14. Lakmé, Act I: "Dôme épais le jasmine" (The Flower Duet) - The Vard Sisters
15. The White Cliffs of Dover - Russell Watson & Vera Lynn
16. Walking in the Air (From “The Snowman”) - Peter Auty

CD3
01. La Traviata, Act I: “Libiamo ne' lieti calici” - Georges Prêtre, RCA Italiana Opera Orchestra, Montserrat Caballé, Carlo Bergonzi & RCA Italiana Opera Chorus
02. Rigoletto, Act III: "La donna è mobile" - Jonas Kaufmann, Pier Giorgio Morandi, Orchestra dell'Opera di Parma & Alberto Bologni
03. O sole mio - Richard Tucker, Alfredo Antonini & The Columbia Concert Orchestra
04. La Wally, Act I: “Ebben? Ne andrò lontano” - Eva Marton, Münchner Rundfunkorchester & Pinchas Steinberg
05. Ave Maria - Plácido Domingo, Die Wiener Sängerknaben, Vienna Symphony Orchestra & Helmut Froschauer
06. I Due Foscari, Act I: “Sì lo sento Iddio mi chiama” - Orchestra del Teatro alla Scala, Luciano Pavarotti & Claudio Abbado
07. Norma, Act I: “Casta diva” - Montserrat Caballé, Ambrosian Opera Chorus, London Philharmonic Orchestra & Carlo Felice Cillario
08. Carmen, Act II: “Votre toast, je peux vous le rendre” - Erwin Schrott, Daniele Rustioni, Radio Symphonie Orchester Wien & Wiener Staatsopernchor
09. Tosca, Act II: “Vissi d'arte” - Leontyne Price, Oliviero de Fabritiis & Rome Opera Orchestra
10. Andrea Chénier, Act III: “La mamma morta” - James Levine, Renata Scotto & National Philharmonic Orchestra
11. Les Contes d'Hoffman, Act II: Barcarolle. Belle nuit - Montserrat Caballé, Shirley Verrett, Anton Guadagno, Ambrosian Opera Chorus, New Philharmonia Orchestra & John McCarthy
12. Ellens Gesang III, D. 839 "Ave Maria" - Erwin Kiennast, José Carreras, Richard Österreicher, Vienna State Opera Chorus & Vienna State Opera Orchestra
13. Rigoletto, Act I: “Caro nome” - Anna Moffo, Sir Georg Solti & RCA Italiana Opera Orchestra
14. Simon Boccanegra, Act I: “Come in quest'ora bruna” - Gianandrea Gavazzeni, RCA Orchestra & Katia Ricciarelli
15. Orfeo Ed Euricice, Act III: “Che farò senza Euridice” - Shirley Verrett, I Virtuosi Di Roma, Renato Fasano & Instrumental Ensemble of the Collegium Musicum Italicum
16. Les pêcheurs de perles, Act I: “Au fond du temple saint” - Jussi Björling, Robert Merrill, Renato Cellini & RCA Victor Symphony Orchestra